What the C100 is for
The form says you fill it in if you want the court to make or change an order about a child and the request is for a child arrangements order, a specific issue order or a prohibited steps order (the "section 8 orders" under the Children Act 1989). The form says it is not for enforcement (that is form C79), and that C2 is used rather than C100 when you apply for an order in existing proceedings or to be joined as a party to them.